Physical chemistry (MSM-ME3)15 ECTS
(englische Bezeichnung: Physical chemistry)
(Prüfungsordnungsmodul: Wahlpflichtmodul Molecular Science)

Lehrveranstaltungen:

• Please check UnivIS for further lectures/seminars
  NB: no overlap with courses in Mandatory Module allowed!

• Mandatory courses:
• A. Lab course:

  Attendance in lab courses is compulsory!

  • Lab Course Advanced Physical Chemistry (SS 2018)
    (Praktikum, 7 SWS, Guido Sauer et al., Zeit n.V., P 0.72, P 0.101; Zeit nach Vereinbarung: Mo-Fr ganztägig (ab 09.04.2018); Anmeldung Mo-Fr 8:00-12:00 (ab 03.04.2018))
• B. Lectures & Seminars:

  please choose additional 6L and 2S, e.g.:

• B1: Characterization of Nanosized Systems (2L)
  • Characterization of Nanosized Systems (WS 2018/2019)
    (Vorlesung, 2 SWS, Dirk Guldi, Di, 14:15 - 16:00, H3 Egerlandstr.3)
• B2: Organic thin films (2L/1S)
  • Organic Thin Films (WS 2018/2019)
    (Vorlesung, 2 SWS, Rainer Fink, Mo, 8:30 - 10:00, H2 Egerlandstr.3; Einzeltermin am 29.10.2018, 8:30 - 10:00, HD)
  • Seminar Organic Thin Films (WS 2018/2019)
    (Seminar, 1 SWS, Rainer Fink et al., Blockveranstaltung; Zeit und Ort nach Vereinbarung)
• B3: Modern Methods in Mass Spectrometry (2L/1S)
  • Modern Methods in Mass Spectrometry (WS 2018/2019)
    (Vorlesung, 2 SWS, Thomas Drewello, Mi, 8:15 - 10:00, 0.113-12)
  • Seminar Modern Methods in Mass Spectrometry (WS 2018/2019)
    (Seminar, 1 SWS, Thomas Drewello et al., Mi, 10:00 - 10:45, H2 Egerlandstr.3)
• B4: Symmetry and Group Theory (2L/1S)
  • Symmetry and Group Theory (WS 2018/2019)
    (Vorlesung, 2 SWS, Jörg Libuda, tbd)
  • Seminar Symmetry and Group Theory (WS 2018/2019)
    (Seminar, 1 SWS, Jörg Libuda et al., Fr, 14:15 - 15:45, P 3.70)
• B5: Interface Science and Catalysis (2L/1S)
  • Advanced Physical Chemistry I - Interface Science and Catalysis (WS 2018/2019)
    (Vorlesung, 2 SWS, Jörg Libuda, Do, 13:15 - 15:00, H3 Egerlandstr.3)
  • Advanced Physical Chemistry I - Seminar Interface Science and Catalysis (WS 2018/2019)
    (Seminar, 1 SWS, Jörg Libuda, Do, 15:00 - 15:45, H3 Egerlandstr.3)
• B6: Solar Energy conversion (2L)
  • Solar Energy Conversion (SS 2018)
    (Vorlesung, 2 SWS, Dirk Guldi, Di, 12:15 - 14:00, H3 Egerlandstr.3)
• B7: Formation and characterization of supramolecular nanoparticles (2L/1S)
  • Formation and Characterization of Supramolecular Nanoparticles (WS 2018/2019)
    (Vorlesung, 2 SWS, Franziska Gröhn, Mo, 14:15 - 16:00, H3 Egerlandstr.3)
  • Seminar Formation and Characterization of Supramolecular Nanoparticles (WS 2018/2019)
    (Seminar, 1 SWS, Franziska Gröhn et al., Do, 12:15 - 13:00, P 3.88)
• B8: Modern techniques in surface science (2L/2S)
  • Modern Techniques in Surface Science (SS 2018)
    (Vorlesung, 2 SWS, Christian Papp et al., Fr, 11:15 - 13:00, H2 Egerlandstr.3)
  • Seminar Modern Techniques in Surface Science (SS 2018)
    (Seminar, 1 SWS, Christian Papp et al., Fr, 13:00 - 13:45, H2 Egerlandstr.3)
• B9: Metallic Nanoparticles in medicine (2L)
  • Metallic Nanoparticles in Medicine (SS 2018)
    (Vorlesung, 2 SWS, Carola Kryschi, Do, 10:30 - 12:00, 0.113-12)
• B10: Catalysis & Kinetics (2L/1S)
  • Catalysis and Kinetics (SS 2018)
    (Vorlesung, 2 SWS, Jörg Libuda, Mo, 13:15 - 15:00, 0.113-12)
  • Seminar Catalysis and Kinetics (SS 2018)
    (Seminar, 1 SWS, Jörg Libuda et al., Mo, 15:00 - 15:45, 0.113-12)
• B11: Advanced Electrochemistry (2L/1S)
  • Energy-related Advanced Electrochemistry (SS 2018)
    (Vorlesung, 2 SWS, Christian Ehli et al., Di, 10:30 - 12:00, 0.113-12)
  • Seminar Energy-related Advanced Electrochemistry (SS 2018)
    (Seminar, 1 SWS, Dirk Guldi et al., Di, 7:30 - 8:15, 0.113-12)

Empfohlene Voraussetzungen:

Admission to the M. Sc. program Molecular Science or Chemistry

Inhalt:

A: Advanced course lab experiments and/or lab project close to actual research topics
B1: Fullerenes; carbon nanotubes; graphene; endohedral metallo fullerenes; peapods; carbon nanohorns and nanoonions; synthesis and analytical techniques.
B2: Preparation techniques (Langmuir-Blodgett films, self-assembled monolayers, sublimation, spin-casting, spraying), self-assembly, structural and spectroscopic analytical techniques, heterostructures, phase diagrams.
B3: Ionisation methods (EI, CI, FD, FI, SIMS, FAB, MALDI and ESI), ion formation mechanisms, analysers (ToF, sector field, quadrupole, ion trap, FT-ICR, orbitrap), tandem mass spectrometry, ion activation and fragmentation, thermochemical and analytical applications.
B4: Symmetry of molecules, symmetry operations and point groups; symmetry of periodic systems; compact course to group theory; group theory and quantum mechanics; symmetry and spectroscopy: vibrational spectroscopies; tensor description of physical properties; band structures.
B5: Surfaces of metals, oxides and ionic crystals; surface analytical techniques; bonding of molecules to surfaces: bonding mechanisms; Blyholder model; adsorbate interactions and superstructures; temperature programmed desorption/reaction; concepts and definitions in catalysis; microkinetics of catalystic processes; transport limitations; surface dynamics and surface kinetics; model catalysis.
B6: Energy portfolio; electron transfer; Si solar cells; dye-sensitized solar cells; organic photovoltaics; multiple excition generation cells; photosynthesis; artificial photosynthesis
B7: Self-assembly of surfactants; self-assembly of more complex amphiphilic molecules; nteraction forces in colloidal systems; osmometry; light scattering; form factor as key to particle shape; dynamic Light Scattering; fractionating Methods for Nanoparticle Analytics; combined Use of Characterization Methods; supramolecular nanoparticles by H-bridges and metal coordination; special Behaviour of polyelectrolytes; nanostructures with polyelectrolytes

Lernziele und Kompetenzen:

The students are able

• to understand the advanced principles of experimental techniques in physical chemistry

• to evaluate the application of experimental and/or theoretical techniques in modern material science/materials research

• to plan and perform advanced lab experiments and/or lab project related to actual research topics in physical chemistry

• to utilize selected preparation techniques for sample preparation

• to apply and understand modern experimental methods for sample characterization

• to interpret and to critically summarize their experimental results in written form (lab report, sometimes in paper-style format).

Literatur:

Manuscripts for most lectures available on StudOn or on lecturers’ website

Bemerkung:

Courses of study for which the module is acceptable: M.Sc. Molecular Science (as mandatory elective module) and M. Sc. Chemistry (as elective module). *)
*) No overlap with courses in Mandatory elective Module “Interface phenomena” or Mandatory Module allowed!

Organisatorisches:

Intended stage in the degree course: Mandatory elective module (Wahlpflichtmodul) or Elective Module (Wahlmodul) semester 1 - 3
Frequency of offer: A: upon appointment with course lab supervisor or research lab supervisors B1-B5, B7: winter term, B6, B8-B11: summer term

Verwendbarkeit des Moduls / Einpassung in den Musterstudienplan:

1. Molecular Science (Master of Science)
   (Po-Vers. 2013 | NatFak | Molecular Science (Master of Science) | Wahlpflichtmodul Molecular Science)

Studien-/Prüfungsleistungen:

Physikalische Chemie - Physical Chemistry (Prüfungsnummer: 30803)

(englischer Titel: Physical Chemistry)

Prüfungsleistung, mündliche Prüfung, Dauer (in Minuten): 45, benotet

Anteil an der Berechnung der Modulnote: 100.0 %

weitere Erläuterungen:
Assessment and examinations: O45 (PL) + LAB (SL): oral examination (45 min, 2 examiners) + lab course protocol(s), ungraded
Calculation of the grade for the module: 100% from oral examination

Prüfungssprache: Englisch

Erstablegung: WS 2018/2019, 1. Wdh.: SS 2019

1. Prüfer:

Jörg Libuda