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Organometallic Catalysis (HomCatal-1)5 ECTS (englische Bezeichnung: Organometallic Catalysis)
Modulverantwortliche/r: Sjoerd Harder Lehrende:
Romano Dorta, Sjoerd Harder
Startsemester: |
SS 2021 | Dauer: |
1 Semester | Turnus: |
jährlich (SS) |
Präsenzzeit: |
45 Std. | Eigenstudium: |
105 Std. | Sprache: |
Englisch |
Lehrveranstaltungen:
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Organometallic Catalysis
(Vorlesung, 2 SWS, Sjoerd Harder et al., Fr, 8:15 - 9:45, H3 Egerlandstr.3; Registration via StudOn. Information on course details and organization by Prof. Harder and Prof. Dorta can be found on their respective StudOn folders – please register there; Fr., 8:15 - 10:00, H2 Egerlandstr.3; The course starts on April 16 with lectures by Prof. Harder, followed on June 11 with lectures by Prof. Dorta)
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Organometallic Catalysis - Seminar
(Seminar, 1 SWS, Sjoerd Harder et al., Time and place by agreement!)
Inhalt:
- Harder: Introduction and basic principles of advanced catalysis, homogeneous vs. heterogeneous catalysis, mechanisms of substrate activation (C=C, C=O), control by ligand and metal choice, classical catalytic cycles: Wilkinson catalyst, C-C cross coupling, hydroformylation, polymerization catalysis, catalysis with main group metals.
Dorta: Review of basic organometallic mechanisms & reactivity (elementary reactions, isolobality); Hydrogenation of alkenes and aromatics; C–C cross coupling; Atom-economical C–C formation (alkene hydroformylation & hydrocyanation, alkene oligomerization, methanol carbonylation); Synthetic fuels form CO (methanol, MTG, Fischer-Tropsch); Alkene metathesis; Selective C–O bond formation (epoxidations and Wacker-type oxidations)
Lernziele und Kompetenzen:
The student
understands basic principles and underlying reaction mechanisms in organometallic catalysis
is able to outline reaction mechanisms and catalytic cycles
knows the tools for the characterization of catalysts and how to evaluate catalyst performance
acquires knowledge on topics of current interest and recent breakthroughs in organometallic catalysis
Bemerkung:
Module compatibility:
Lecture module within the Compulsory Elective module "Advances in Homogenous Catalysis" in M. Sc. Chemistry or Molecular Science (20 ECTS in total, graded)
as Elective Module in M. Sc. Chemistry or Molecular Science (5 ECTS, ungraded)
Organisatorisches:
- The module "Organometallic Catalysis" will be taught only in summer term!
The module "Organometallic Catalysis" will be taught online (synchronous/asynchronous) until further notice
Students have to register for this module (check registration periods)!
Registration/further information via StudOn!
Studien-/Prüfungsleistungen:
Metalorganic Catalysis (Prüfungsnummer: 65211)
- Prüfungsleistung, mündliche Prüfung, Dauer (in Minuten): 20, benotet, 5 ECTS
- Anteil an der Berechnung der Modulnote: 100.0 %
- weitere Erläuterungen:
O20(PL): Oral examination (20 minutes) or alternative examination according to FAU-Corona Statutes!
- Prüfungssprache: Englisch
- Erstablegung: SS 2021, 1. Wdh.: WS 2021/2022
1. Prüfer: | Romano Dorta, | 2. Prüfer: | Sjoerd Harder |
- Termin: 13.09.2021, Ort: Egerlandstrasse. 1, Raum A1.42
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