Organometallic Catalysis (HomCatal-1)5 ECTS
(englische Bezeichnung: Organometallic Catalysis)
(Prüfungsordnungsmodul: Organometallic Catalysis)

Lehrveranstaltungen:

• • Organometallic Catalysis
    (Vorlesung mit Übung, 3 SWS, Sjoerd Harder et al., Fr, 8:15 - 9:45, H2 Egerlandstr.3; Seminar: time and place by agreement)
  • Organometallic Catalysis - Seminar
    (Seminar, 1 SWS, Sjoerd Harder et al., Time and place by agreement!)

Inhalt:

• Harder: Introduction and basic principles of advanced catalysis, homogeneous vs. heterogeneous catalysis, mechanisms of substrate activation (C=C, C=O), control by ligand and metal choice, classical catalytic cycles: Wilkinson catalyst, C-C cross coupling, hydroformylation, polymerization catalysis, catalysis with main group metals.

• Dorta: Review of basic organometallic mechanisms & reactivity (elementary reactions, isolobality); Hydrogenation of alkenes and aromatics; C–C cross coupling; Atom-economical C–C formation (alkene hydroformylation & hydrocyanation, alkene oligomerization, methanol carbonylation); Synthetic fuels form CO (methanol, MTG, Fischer-Tropsch); Alkene metathesis; Selective C–O bond formation (epoxidations and Wacker-type oxidations)
  

Lernziele und Kompetenzen:

The student

• understands basic principles and underlying reaction mechanisms in organometallic catalysis

• is able to outline reaction mechanisms and catalytic cycles

• knows the tools for the characterization of catalysts and how to evaluate catalyst performance

• acquires knowledge on topics of current interest and recent breakthroughs in organometallic catalysis
  

Bemerkung:

Module compatibility:

• Lecture module within the Compulsory Elective module "Advances in Homogenous Catalysis" in M. Sc. Chemistry or Molecular Science (20 ECTS in total, graded)
  

• as Elective Module in M. Sc. Chemistry or Molecular Science (5 ECTS, ungraded)

Organisatorisches:

• The module "Organometallic Catalysis" will be taught only in summer term!

• Students have to register for this module (check registration periods)!

• Registration/further information via StudOn!

Verwendbarkeit des Moduls / Einpassung in den Musterstudienplan:

1. Molecular Science (Master of Science): ab 1. Semester
   (Po-Vers. 2020w | NatFak | Molecular Science (Master of Science) | Compulsory elective module | Advances in Homogenous Catalysis | Organometallic Catalysis)
2. Molecular Science (Master of Science): ab 1. Semester
   (Po-Vers. 2020w | NatFak | Molecular Science (Master of Science) | Elective modules | Organometallic Catalysis)

Studien-/Prüfungsleistungen:

Metalorganic Catalysis (Prüfungsnummer: 65211)

Prüfungsleistung, mündliche Prüfung, Dauer (in Minuten): 20, benotet, 5 ECTS

Anteil an der Berechnung der Modulnote: 100.0 %

weitere Erläuterungen:
O20(PL): Oral examination (20 minutes) or alternative examination according to FAU-Corona Statutes!

Prüfungssprache: Englisch

Erstablegung: SS 2022, 1. Wdh.: WS 2022/2023

1. Prüfer:

Romano Dorta,

2. Prüfer:

Sjoerd Harder